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Chromate Removal by Dithionite-Reduced Clays: Evidence from Direct X-Ray Adsorption Near Edge Spectroscopy (Xanes) of Chromate Reduction at Clay Surfaces
Illite IMt-2 Kaolinite KGa-2 Montmorillonite Reduction Smectite Sorption SWa-1 SWy-1 XANES
2011/12/6
Abstract: Chromium(VI) in the environment is of particular concern because it is toxic to both plants and animals, even at low concentrations. As a redox-sensitive element, the fate and toxicity of ch...
Mossbauer Spectroscopic Evidence for Citrate-Bicarbonate-Dithionite Extraction of Maghemite from Soils
Mossbauer spectroscopy Soil genesis
2011/12/1
Abstract: In a previous paper, we used powder X-ray diffraction and changes in magnetic susceptibility to argue the importance of pedogenic maghemite to soils and the efficacy of the chemical extracta...
Acidified Oxalate and Dithionite Solubility and Color of Synthetic, Partially Oxidized Al-Magnetites and their Thermal Oxidation Products
Aluminum substitution Electron microscopy Hematite Maghemite Magnetite Oxidation Solubility
2011/12/1
Abstract: Submicron-sized (∼3–60 nm) powders of Al-substituted magnetite were synthesized in the laboratory by precipitation methods by mixing appropriate molar volumes FeCl2, FeCl3 and AlCl3 so...
Dithionite as a Dissolving Reagent for Goethite in the Presence of EDTA and Citrate. Application to Soil Analysis
Dithionite Goethite Iron analysis Iron dissolution
2011/12/31
A synergistic effect of reductant and complexant is observed in the dissolution of goethite by dithionite and citrate or EDTA. The rate data are interpreted using the surface complexation approach to ...
Optical Density of Vertisol Clay Suspensions in Relation to Sediment Volumes and Dithionite-Citrate-Bicarbonate-Extractable Iron
Beidellite Extractable Fe Fabric Optical density Tactoid Vertisol
2012/1/11
Clay fractions of eight vertisols and vertisolic soils from Israel were found to consist principally of a Fe-rich beidellite. Sediment volumes of Na-clay suspensions, obtained in measuring cylinders a...
Preparation and Handling of Dithionite-Reduced Smectite Suspensions
Dithionite Iron Nontronite Reduction Reoxidation Smectite
2012/2/3
Using Garfield, Washington, nontronite as the model mineral system, methods and apparatus were developed to prepare reduced suspensions in citrate-bicarbonate-dithionite (CBD) solution. These techniqu...
Reduction and Oxidation of Fe3+ in Dioctahedral Smectites—1: Reduction with Hydrazine and Dithionite
Reduction Oxidation Dioctahedral Smectites Hydrazine Dithionite
2012/2/13
Hydrazine and dithionite, both of which are strong reducing agents, react differently with various dioctahedral smectites. Both the nature of the reducing agent and the structure of the clay affect th...