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以具有不同孔结构的微孔分子筛为酸性组分,制备了含分子筛的硫化态NiMoP/Al2O3催化剂。考察了临氢条件下邻二甲苯的异构化反应,采用XRD、N2吸附脱附、吡啶吸附红外和SEM等表征手段对分子筛及催化剂样品进行物化性质分析。结果表明,分子筛的孔结构和酸性中心的可接近性是影响该催化剂体系上邻二甲苯的反应活性及产物分布的主要因素。在反应温度为300℃、氢分压40 MPa、氢气/邻二甲苯(体积...
在氢分压4.0 MPa、523~723 K硫化温度范围内,考察了硫化温度对含和不含柠檬酸的NiW/Al2 O3催化剂的4,6-二甲基二苯并噻吩(4,6-DMDBT)加氢脱硫活性的影响,并采用X射线光电子能谱(XPS)和高分辨透射电镜(HRTEM)对硫化态催化剂进行了表征。结果表明,含柠檬酸的NiW/Al2 O3催化剂的加氢脱硫活性随硫化温度的变化规律与无柠檬酸催化剂相似,脱硫活性均在673 K时达...
Hydrogenation of naphthalene in the presence of CO was examined as a step in the organic hydride method for utilizing low grade hydrogen. Development of CO-tolerant hydrogenation catalysts will allow ...
A series of Ru/Mn/Al2O3 catalysts with different concentrations of manganese were investigated on catalyst characterization and activity for Fischer-Tropsch synthesis in a continuous stirred tank reac...
To suppress total oxidation and increase the CO selectivity of high-pressure oxidative reforming of methane, preparation parameters of KW22;Ni/α-Al2O3 catalyst were optimized. The target preparatio...
Removal of phenol by wet air oxidation was conducted with 1 wt% Pt/Al2O3 catalyst in a batch reactor and in a continuous flow fluidized bed reactor with air lift tube operated at 423 K and 1.4 MPa. Af...
The catalytic activity of iron oxide composite catalyst (ZrO2–Al2O3–FeOx) was investigated for converting aromatic compounds derived from plant biomass into useful aromatics. Catalytic cracking of lig...
Ru/Mn/Al2O3 and Ru/Al2O3 catalysts, which prepared with various ruthenium precursors into impregnation method, were investigated for Fischer-Tropsch (FT) synthesis in a continuous stirred tank reactor...
采用浸渍法制备了LiLaNi/Al2O3催化剂,并用XRD, SEM, TPR等对其进行了表征. Li的加入对催化剂的结构、NiAl2O4的结晶度及Ni2+离子还原能力都有较大影响. 以甲苯为焦油的模型化合物,在固定床反应器中对高温焦炉煤气中焦油催化转化反应进行了评价. 结果显示,Li能显著改善LaNi/Al2O3催化剂的催化反应活性,提高产物中H2的含量. 在750℃、水/碳比为2.0的条件下,...
Selective reduction of NO using fatty acid methyl esters (FAMEs) as the reducing agents was investigated over 3 wt% Ag/Al2O3 catalyst. NO reduction with C6-C14 saturated FAMEs showed volcano-type temp...
10 wt%Ru-Al2O3 catalysts with uniform pore sizes in the range of 3-7 nm were prepared by the alkoxide method by changing the added amount of H2O highly diluted with butanol at the gelation stage of s...
Durability of the Ru/CeO2/γ-Al2O3 catalyst for steam reforming of dodecane was investigated using a packed bed type tubular reactor with multiple gas sampling ports along its length. The catalyst, bef...
The present study evaluated 129Xe NMR spectroscopy for the analysis of Co-Mo/Al2O3 hydrodesulfurization catalyst. This study also reconsidered the conventional interpretation of 129Xe NMR spectroscop...
Steam reforming of dimethyl ether, DME, over Cu/ZnO/ZrO2 and γ-Al2O3 mixed catalysts prepared by the extrusion technique was investigated. The catalysts were characterized by BET, pore-size distribut...
Ru/Al2O3 catalyst was investigated by using Mn addition for Fischer-Tropsch synthesis under pressurized conditions. On the basis of catalyst activity, selectivity and deactivation, small amount of Mn...

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